New Dinuclear Ru2(CO)4Sawhorse-Type Complexes Containing Bridging Carboxylato Ligands
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منابع مشابه
Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry
The mononuclear complexes [(g-C5Me5)IrCl(L )] (1), [(g-C5Me5)RhCl(L )] (2), [(g-p-PrC6H4Me)RuCl(L )] (3) and [(gC6Me6)RuCl(L )] (4) have been synthesised from pyrazine-2-carboxylic acid (HL) and the corresponding complexes [{(gC5Me5)IrCl2}2], [{(g -C5Me5)RhCl2}2], [{(g -p-PrC6H4Me)RuCl2}2], and [{(g -C6Me6)RuCl2}2], respectively. The related dinuclear complexes [{(g-C5Me5)IrCl}2(l-L )] (5), [{(...
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The thermal reaction of Ru3(CO)12 with the biologically active acids acetyl salicylic acid (Aspirin), a-methyl-4-(isobutyl)phenylacet acid (Ibuprofen) and 3a,7a,12a-trihydroxy-5b-cholanic acid (cholic acid) in refluxing tetrahydrofuran, followed by addition of tripheny phosphine, gives the dinuclear complexes Ru2(CO)4(OOCR)2(PPh3)2 (1: R = C6H4-2-OCOMe, 2: R = CHMe-C6H4-4-Bu , 3: C23H39O3 The s...
متن کاملCationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands.
Hydride-abstraction reactions of hydrido(dihydrogermyl) complexes [MH(GeH2Trip)(dcpe)] [M = Pt, Pd, Trip = 9-triptycyl, dcpe = 1,2-bis(dicyclohexylphosphino)ethane] with B(C6F5)3 led to the unexpected formation of new cationic (μ-germyl)(μ-hydrido) dinuclear platinum and palladium complexes, [{M(dcpe)}2(μ-GeHTrip)(μ-H)](+).
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2009
ISSN: 0044-2313,1521-3749
DOI: 10.1002/zaac.200800385